New Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation
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New Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation
Shang, Rui
Springer Verlag, Singapore
07/2018
216
Mole
Inglês
9789811098130
15 a 20 dias
454
Descrição não disponível.
Introduction to Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation.- Part I New Carbon-Carbon Bond Formation Methodologies Based on Decarboxylation.- Transition-Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplings.- Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with Aryl and Alkenyl Halides.- Synthesis of Polyfluorobiaryls via Copper-Catalyzed Decarboxylative Couplings of Potassium Polyfluorobenzoates with Aryl Bromides and Iodides.- Palladium-Catalyzed Decarboxylative Couplings of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides and Triflates.- Construction of C(sp3)-C(sp2) Bonds via Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryl)acetate Salts with Aryl Halides.- Synthesis of ?-Aryl Nitriles and ?-Aryl Acetate Esters via Palladium-Catalyzed Decarboxylative Couplings of ?-Cyano Carboxylate Salts and Malonate Monoester Salts with Aryl Halides.- Palladium-Catalyzed Decarboxylative Couplings of Nitrophenyl Acetate Salts and Its Derivatives with Aryl Halides.- Palladium-Catalyzed Decarboxylative Benzylation of ?-Cyano Aliphatic Carboxylate Salts with Benzyl Electrophiles.- Part II New Carbon-Carbon Bond Formation Methodologies Based on Iron-Catalyzed C-H Activation.- Recent Develpments of Iron-Catalyzed Directed C-H Activation/C-C Bond Formation Reactions.-?-Arylation of Carboxamides via Iron-Catalyzed C(sp3)-H Bond Activation.- Iron-Catalyzed C(sp2)-H and C(sp3)-H Bond Functionalization with Organoboron Compounds.
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Metal catalysis;C-C bond formation;Decarboxylation;Palladium-catalyzed decarboxylative coupling;Carboxylate salts;Iron-catalyzed C-H ativation;Copper-catalyzed decarboxylative coupling;C-H functionalization
Introduction to Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation.- Part I New Carbon-Carbon Bond Formation Methodologies Based on Decarboxylation.- Transition-Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplings.- Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with Aryl and Alkenyl Halides.- Synthesis of Polyfluorobiaryls via Copper-Catalyzed Decarboxylative Couplings of Potassium Polyfluorobenzoates with Aryl Bromides and Iodides.- Palladium-Catalyzed Decarboxylative Couplings of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides and Triflates.- Construction of C(sp3)-C(sp2) Bonds via Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryl)acetate Salts with Aryl Halides.- Synthesis of ?-Aryl Nitriles and ?-Aryl Acetate Esters via Palladium-Catalyzed Decarboxylative Couplings of ?-Cyano Carboxylate Salts and Malonate Monoester Salts with Aryl Halides.- Palladium-Catalyzed Decarboxylative Couplings of Nitrophenyl Acetate Salts and Its Derivatives with Aryl Halides.- Palladium-Catalyzed Decarboxylative Benzylation of ?-Cyano Aliphatic Carboxylate Salts with Benzyl Electrophiles.- Part II New Carbon-Carbon Bond Formation Methodologies Based on Iron-Catalyzed C-H Activation.- Recent Develpments of Iron-Catalyzed Directed C-H Activation/C-C Bond Formation Reactions.-?-Arylation of Carboxamides via Iron-Catalyzed C(sp3)-H Bond Activation.- Iron-Catalyzed C(sp2)-H and C(sp3)-H Bond Functionalization with Organoboron Compounds.
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