Functionalization of Carborane via Carboryne Intermediates
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Functionalization of Carborane via Carboryne Intermediates
Zhao, Da
Springer Verlag, Singapore
06/2018
170
Mole
Inglês
9789811093890
15 a 20 dias
3276
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Introduction.- Regioselective Insertion of ?-Carborynes into ?-C?H Bond of Tertiary Amines.- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C-H Insertion Reaction.- Reaction of ?-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition.- 1,3-Dehydro-?-Carborane: Generation and Reaction with Arenes.- Ene Reaction of 1,3-Dehydro-?-Carborane.- Cage Boron Arylation of ?-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling.- Conclusion.- Experimental Section.
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Synthetic Methods;Carborane Functionalization;Cluster Compounds;Cycloaddition;C?H Insertion;Multiple Bonds;Carboryne
Introduction.- Regioselective Insertion of ?-Carborynes into ?-C?H Bond of Tertiary Amines.- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C-H Insertion Reaction.- Reaction of ?-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition.- 1,3-Dehydro-?-Carborane: Generation and Reaction with Arenes.- Ene Reaction of 1,3-Dehydro-?-Carborane.- Cage Boron Arylation of ?-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling.- Conclusion.- Experimental Section.
Este título pertence ao(s) assunto(s) indicados(s). Para ver outros títulos clique no assunto desejado.
